The BBC presenter has made a habit out of hitting the right notes when it comes to fashion.
Scroll down for more of Alex Scott’s fashionable looks
And the 39-year-old has continued to push boundaries with what she wears.
Scott was in action on Friday as she hosted the Beeb’s inaugural charity fundraiser, Children In Need.
Now, she has shared some behind-the-scenes pictures from the night.
The ex-Arsenal star looked dazzling in black blazer and trouser combo to TV viewers.
While later on Alex donned a figure-hugging black dress to really glam up proceedings.
She matched the classy outfit with a diamond choker.
She captioned the nine pics: “An incredible evening once again being a small part of this ICONIC show that I have watched since I was a kid. It’s a huge honour to grace that stage alongside my co-hosts and to see first hand all the efforts put in by everyone to bring it all together.
“A staggering amount was raised once again, everyone coming together to help change lives is something so special. So many magical moments like @vernonkay to everyone at the @bbctheoneshow and the Challenge Squad to the studio audience and everyone at home cheering everyone on.
“My heart is full thinking about it all.”
Fans were ecstatic they got to see Alex’s stunning ensemble on social media.
One wrote: “So gorgeous.”
A second added: “Amazing evening and you looked absolutely incredible.”
A third posted: “Beautiful as usual.”
While a fourth shared: “What a role model for the young girls.”